红色黏土型金矿中金与其伴生元素的关系

红色黏土型金矿是近年来发现的金矿新类型。利用中子活化分析方法研究了As、Sb等元素与Au的相关关系,为红色黏土型金矿勘探提供了一种新的思路,并通过分析含与其它微量元素的关系,可以看出,该金矿床为一种除金以外的多金属金矿,可以综合利用。     

锑精矿中锡的快速测定

报道了大量锑中微量锡的分离方法。在一定的碱量条件下，使锑大部分沉淀，分离后的溶液用水杨基荧酮进行锡的光度法测定。     

Self‐Assembly of a 3d–5f Trinuclear Single‐Molecule Magnet from a Pentavalent Uranyl Complex

Mixed‐metal uranium compounds are very attractive candidates in the design of single‐molecule magnets (SMMs), but only one 3d–5f hetero‐polymetallic SMM containing a uranium center is known. Herein, we report two trimeric heterodimetallic 3d–5f complexes self‐assembled by cation–cation interactions between a uranyl(V) complex and a TPA‐capped M^II complex (M=Mn ( 1 ), Cd ( 2 ); TPA=tris(2‐pyridylmethyl)amine). The metal centers were strategically chosen to promote the formation of discrete molecules rather than extended chains. Compound 1 , which contains an almost linear {Mn? O?U?O? Mn} core, exhibits SMM behavior with a relaxation barrier of 81±0.5 K—the highest reported for a mono‐uranium system—arising from intramolecular Mn–U exchange interactions combined with the high Ising anisotropy of the uranyl(V) moiety. Compound 1 also exhibits an open magnetic hysteresis loop at temperatures less than 3 K, with a significant coercive field of 1.9 T at 1.8 K.     

From Ore to Tool – Iron Age Iron Smelting in the Largest and Oldest Meteorite Crater in the World

The Vredefort Impact Structure in South Africa is the biggest and oldest remnant meteorite impact crater in the world where various ancient cultures thrived. In this paper some light will be shed on the Iron Age, iron smelting aspects of the people that inhabited the area and the results of a laboratory study of iron artefacts and a possible source of iron ore in the region is given. A sectional piece from a hoe manufactured in a small bloomery furnace was polished and etched and subsequently analyses with SEM and Mössbauer techniques were obtained. The hoe has a typical cast iron composition (2.9% C, 0.1% Mn, 0.4% Si, 0.4% P and 96.2% Fe, all wt.%) and contains many slag inclusions with wustite dendrites. The Mössbauer spectrum consisted of iron (86%), wustite (5%) and oxihydroxide (9%) and the thin (200 μm) corrosion layer consisted of hematite (55%) and oxihydroxides (45%). At a furnace site, various slag clumps (26.3% C, 24.8% SiO₂, 11.3% Al₂O₃, 1.3% P₂O₅, 1.0% K₂O, 0.4% CaO and 30.2 FeO, all wt.%, average of four samples) and iron nodules (7.6% C, 6.0% Mn, 4.3% Si, 1.4% Al, 80.7% Fe, all wt.%) were found. The Mössbauer spectrum of the slag consisted of iron (7%), magnetite (56%), fayalite (2%) and oxihydroxides (35%) and that of the iron nodules yielded iron (28%), wustite (12%), magnetite (20%) and oxihydroxides (40%). A possible ore source containing 84% FeO, 7% of Al₂O₃ and SiO₂ (all in wt.%) and minor impurities is located a few kilometers from the furnace site, yielding a Mössbauer spectrum consisting of hematite (70%) and oxihydroxides (30%).     

Weyl型代数的环论性质

设A是代数闭域k上有单位元1的交换结合代数，D是A的交换κ-导子组成的非零k-向量空间，苏育才与赵开明引进Weyl型代数A[D]并且证明了结合代数A[D]是单代数当且仅当A是D-单的且k1[D]在A上的作用为忠实的,通过证明A[D]与smash product A#U(D)同构，我们给出了这一结果的一个纯环论的证明，同时给出了A[D]的一个Ore扩张实现。     

ICP－AES中迭代干扰校正法在稀土配分上的应用

本文采用干扰系数迭代校正法测定稀土氧化物富集样中稀土元素的含量。应用迭代校正程序，计算机可以迅速得出准确结果。为了减少分析波长选择的盲目性，建立了一套扫描峰形图谱库。将ＩＣＰ－ＡＥＳ与微机联用直接选出了各个稀土元素的最优测量条件，综合确定仪器的最佳工作参数。本法的回收率为９０～１０８％，Ｒ．Ｓ．Ｄ小于６％。     

MICROFOSSILS FROM LATE PROTEROZOIC MANGANESE ORE DEPOSITS IN WESTERN HUNAN PROVINCE AND EASTERN GUIZHOU PROVINCE, SOUTH CHINA

Abundant microfossils and organic residuals have been discovered by SEM and normal palynological maceration from manganese ore beds intercalated in late Proterozoic glacial rock units in western Hunan Province and eastern Guizhou Province. Taking isotopic dating into consideration, the age of manganese ore deposits in both regions is suggested to be about 750 Ma. A distinct character is that a great quantity of colonial microfossil——Sphaerocongregus (or Bavlinella) and their degradational variants have been obtained from rhodochrosite. Their biological and biochemical functions, combined with the geochemical effect of manganese in different ways, may play an important role in the manganese cycle.     

燃烧法测定氧化矿捕收剂吸附量

虽然有很多现代测试技术可以用来测定脂肪酸类捕收剂在氧化矿表面的吸附量,但灵敏、方便和实用的方法并不多.燃烧法测定脂肪酸类捕收剂在氧化矿表面的吸附量具有速度快,设备简单的优点,具有很强的实用性,非常适合于氧化矿浮选捕收剂的试验研究.主要对燃烧法中差热分析法、载流燃烧法和顶空气相红外分析法的发展现状与应用进行了评述.     

多金属结核/结壳中稀土元素的富集特征及其资源效应

多金属结核/结壳是海洋中最重要的固体沉积矿产之一,蕴藏丰富的铁、锰、铜、钴、镍等金属元素,也是稀土元素的富集体.利用等离子质谱仪/光谱仪对太平洋、大西洋、印度洋及南海北部海多金属结核/结壳11个样品25份试样的稀土含量进行了分析,多金属结核/结壳中稀土平均含量为1265 57×10-6,其中结核平均含量为1096.96×10-6,结壳平均含量1623.88×10-6,人人超过地壳和玑积岩的平均含量.稀土元素的富集主要受控于结核/结壳中铁、锰氧化物及粘土矿物对海水和沉积物中稀土元素的吸附作用,Ce元素高度富集,使其成为多金属结核/结壳矿产开发中可能最先利用的稀土元素之一.     

激光诱导击穿光谱定量分析锂矿石中锂元素

锂元素具有优良的物理和化学性能,因而在军事、电池、特种合金、受控热核反应等领域具有重要作用。现有的锂矿石分析主要是基于酸分解的原子吸收光谱、电感耦合等离子体质谱或原子发射光谱等离线方法。激光诱导击穿光谱(LIBS)是一种无需样品制备、适用于低原子序数元素(包括锂)的原子发射光谱方法。采用LIBS技术,实验采集了11种锂矿石成分分析标准物质的等离子体发射光谱,分别在610.35和670.78 nm附近观测到了Li的特征峰,但由于谱线的重叠,无法应用单变量线性回归进行建模。在全谱积分强度标准化基础上,分别使用偏最小二乘回归(PLSR)和基于主成份分析的支持向量回归(PCA+SVR)对锂矿石标准物质中的锂含量进行建模。校准模型的相关参数通过留一组交叉验证均方根误差(RMSECV)来确定。结果表明,相较于PCA+SVR校准模型,PLSR的决定系数(R2)更大,校准均方根误差(RMSEC)更小,但预测均方根误差(RMSEP)远大于RMSEC,存在过拟合现象。另一方面,PCA+SVR计算得到的RMSEP和平均相对误差(MRE)相对于PLSR更小,因此认为PCA+SVR模型拥有更好适应度。从而证明,LIBS技术可以实现锂矿石中Li含量的分析,有望应用于位于传送带上锂矿石的原位在线定量分析。